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There has been longstanding controversy about whether the influence of lateral variations in core-mantle boundary heat flow can be detected in paleomagnetic records of geomagnetic field behavior. Their signature is commonly sought in globally distributed records of virtual geomagnetic pole (VGP) paths that have been claimed to exhibit specific longitudinal preferences during polarity transitions and excursions. These preferences have often been linked to thermal effects from large low seismic velocity areas (LLVPs) in the lowermost mantle, but the results have been contested because of potential sensitivity to sparse temporal and spatial sampling. Recently developed time varying global paleofield models spanning various time intervals in 1–100 ka, three of which include excursions, allow us to complement assessments of spatial distributions of transitional VGP paths with distributions of minimum field intensity. Robustness of the results is evaluated using similar products from four distinct numerical dynamo simulations with and without variable thermal boundary conditions and including stable geomagnetic polarity, excursions and reversals. We determine that VGP distributions are less useful than minimum field intensity in linking the influences of thermal CMB structure to geographical variations in actual paleofield observables, because VGP correlations depend strongly on good spatial sampling of a sufficient number of relatively rare events. These results provide a basis for evaluating comparable observations from four paleofield models. The distribution of VGP locations provide unreliable results given the restricted time span and available data locations. Rough correlations of global distributions of minimum intensity with areas outside the LLVPs give some indications of mantle control during excursions, although the results for the eastern hemisphere are complex, perhaps highlighting uncertainties about the hemispheric balance between thermal and compositional variations in the lowermost mantle. However, access to other geomagnetic properties (such as intensity and radial field at the CMB) provides a strong argument for using extended and improved global paleofield models to resolve the question of mantle influence on the geodynamo from the observational side. 

Abstract Earth's core has produced a global magnetic field for at least the last 3.5 Gyrs, presently sustained by inner core (IC) growth. Models of the core with high thermal conductivity suggest potentially insufficient power available for the geodynamo prior to IC formation ∼1 Ga. Precipitation of silicon from the liquid core might offer an alternative power source for the ancient magnetic field, although few estimates of the silicon partition coefficient exist for conditions of the early core. We present the first ab initio determination of the silicon partition coefficient at core‐mantle boundary conditions and use these results to confirm a thermodynamic description of partitioning that is integrated into a model of coupled core‐mantle thermal evolution. We show that models including precipitation of silicon can satisfy constraints of IC size, mantle convective heat flux, mantle temperature and a persistent ancient geodynamo, and favor an oxygen poor initial core composition. 

Abstract We present a joint experimental‐modeling investigation of core cooling in small terrestrial bodies. Significant amounts of light elements (S, O, Mg, Si) may compose the metallic cores of terrestrial planets and moons. However, the effect of multiple light elements on transport properties, in particular, electrical resistivity and thermal conductivity, is not well constrained. Electrical experiments were conducted at 10 GPa and up to 1850 K on high‐purity powder mixtures in the Fe‐S‐O(±Mg, ±Si) systems using the multianvil apparatus and the four‐electrode technique. The sample compositions contained 5 wt.% S, up to 3 wt.% O, up to 2 wt.% Mg, and up to 1 wt.% Si. We observe that above the eutectic temperature, electrical resistivity is significantly sensitive to the nature and amount of light elements. For each composition, thermal conductivity‐temperature equations were estimated using the experimental electrical results and a modified Wiedemann‐Franz law. These equations were implemented in a thermochemical core cooling model to study the evolution of the dynamo. Modeling results suggest that bulk chemistry significantly affects the entropy available to power dynamo action during core cooling. In the case of Mars, the presence of oxygen would delay the dynamo cessation by up to 1 Gyr compared to an O‐free, Fe‐S core. Models with 3 wt% O can be reconciled with the inferred cessation time of the Martian dynamo if the core‐mantle boundary heat flow falls from >2 TW to ~0.1 TW in the first 0.5 Gyr following core formation. 

Abstract The apparent end of the internally generated Martian magnetic field at 3.6–4.1 Ga is a key event in Martian history and has been linked to insufficient core cooling. We investigate the thermal and magnetic evolution of the Martian core and mantle using parameterized models and considered three improvements on previous studies. First, our models account for thermal stratification in the core. Second, the models are constrained by estimates for the present‐day areotherm. Third, we consider core thermal conductivity,, values in the range 5–40 Was suggested by recent experiments on iron alloys at Mars core conditions. The majority of our models indicate that the core of Mars is fully conductive at present with core temperatures greater than 1940 K. All of our models are consistent with the range ofW. Models with an activation volume of 6 (0)require a mantle reference viscosity of Pa s.